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Influence of Epoxy Functional Chain-Extenders on the Thermal and Rheological Properties of Bio-Based Polyamide 10.10

Erdmann, Rafael; Rennert, Mirko; Meins, Thomas (2023)

Polymers 2023, 15 (17), S. 3571.
DOI: 10.3390/polym15173571


Open Access Peer Reviewed
 

Bio-based polyamide 10.10 (PA 10.10) has excellent properties compared to other biobased  polymers such as polylactic acid (PLA) or polyhydroxyalkanoates (PHAs) and is therefore used in more technical applications where higher strength is required. For foam and filament extrusion,a good balance between strength and stiffness of the  polymer is needed. Therefore, two commercial chain-extenders (Joncryl® ADR types) with different epoxy functionalities are used to modify the melt properties of PA 10.10. The chain-extenders are used in a concentration range up to 1.25 wt.%. The range of glass transition temperature widens with increasing Joncryl® content, and the apparent activation energy shows a maximum at a concentration of 0.5 wt.%. Furthermore, the melting temperatures are constant and the crystallinity decreases with increasing chain-extender content due to the formation of branches. During the second heating run, a bimodal melting peak appeared, consisting of 𝛼-triclinic and pseudo 𝛾-hexagonal crystals. The weight average molar masses (Mw) measured by gel permeation chromatography (GPC) increased linearly with increasing ADR 4400 content. In contrast, the compounds containing ADR 4468 show a maximum at 0.5 wt.% and it begins to decrease thereafter. The rheological data show an increase in viscosity with increasing chainextender content due to branch formation. ATR spectra of the compounds show a decrease at the wavelength of the primary (3301 cm−1) and secondary (1634 cm−1) (-NH stretching in PA 10.10) amine, indicating that chain-extension, e.g., branching, takes place during compounding.

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Stellungnahme des FINSOZ e.V. zum Referentenentwurf des Bundesministeriums für Gesundheit eines Gesetztes zur Beschleunigung der Digitalisierung des Gesundheitswesens (Digital Gesetz - DigiG)

Wolff, Dietmar (2023)

Bundesministerium für Gesundheit.


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Das Forschungsprojekt Eisbatterie - Forschungspodcast

Dölz, Michael (2023)

Spotify, Apple Podcasts, Anchor, You Tube, amazon music, Wissenschafts Podcasts.



V-Commerce: virtuelle Welten im Online Shopping und wie wir mit Ihnen umgehen sollten.

Wagener, Andreas (2023)

Naskrent, Julia / Marcus Stumpf, Marcus / Westphal, Jürgen / Rothe, Lena (Hrsg.). Marketing & Innovation 2023: Future Shopping – Der Handel in der (Nach-)Corona-Zeit, S. 93 -110, Springer.
DOI: 10.1007/978-3-658-41309-5


Peer Reviewed
 

Corona hat uns alle gelehrt, dass auch grundsätzlich in virtuellen Umgebungen Leben möglich scheint – sei es im Home-Office oder bei digitalen Veranstaltungen. Vermutlich ist es mehr als ein zeitlicher Zufall, dass virtuelle Shopping- und Marketing-Umgebungen gerade in dieser Zeit einen neuen Trend beschreiben. Nicht erst seit Mark Zuckerberg das „Metaverse“ ausgerufen hat, bilden sich virtuelle Welten, in denen digitale Avatare und „Digital Humans“ miteinander interagieren, in denen virtuelle, immaterielle „Sachgüter“ - virtuelle Kunst, Mode, Luxusgüter und Immobilien als „unique“ NFTs handelbar sind und die zunehmend auch für die Führung von „Offline“-Marken genutzt werden.

Der angestrebte Artikel versucht, das Marktsystem der Metaversen zu erfassen und widmet sich dabei vor allem den Chancen, die sich traditionellen Unternehmen aus der analogen oder „klassischen“ Online-Welt eröffnen: Welche Geschäftsmodelle bestehen – auch für kleinere Unternehmen und den Mittelstand? Welches sind die Erfolgsfaktoren – für den virtuellen Handel und für ein nachhaltiges Branding? Welche Hürden sind dabei zu überwinden? Und wie sehen Erfolg versprechende Konzepte aus?

Letztlich geht es im Kern um die Frage: Ist die Zukunft des Shoppings virtuell?

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IT-Report für die Sozialwirtschaft 2023

Kreidenweis, Helmut; Wolff, Dietmar (2023)


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Improvement of the Thermo-Oxidative Stability of Biobased Poly(butylene succinate) (PBS) Using Biogenic Wine By-Products as Sustainable Functional Fillers

Hiller, Benedikt; Rennert, Mirko (2023)

Polymers.
DOI: 10.3390/polym15112533


Open Access
 

Biobased poly(butylene succinate) (PBS) represents one promising sustainable alternative to petroleum-based polymers. Its sensitivity to thermo-oxidative degradation is one reason for its limited application. In this research, two different varieties of wine grape pomaces (WPs) were investigated as fully biobased stabilizers. WPs were prepared via simultaneous drying and grinding to be used as bio-additives or functional fillers at higher filling rates. The by-products were characterized in terms of composition and relative moisture, in addition to particle size distribution analysis, TGA, and assays to determine the total phenolic content and the antioxidant activity. Biobased PBS was processed with a twin-screw compounder with WP contents up to 20 wt.-%. The thermal and mechanical properties of the compounds were investigated with DSC, TGA, and tensile tests using injection-molded specimens. The thermo-oxidative stability was determined using dynamic OIT and oxidative TGA measurements. While the characteristic thermal properties of the materials remained almost unchanged, the mechanical properties were altered within expected ranges. The analysis of the thermo-oxidative stability revealed WP as an efficient stabilizer for biobased PBS. This research shows that WP, as a low-cost and biobased stabilizer, improves the thermo-oxidative stability of biobased PBS while maintaining its key properties for processing and technical applications.

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Explaining rehearsals of a symphony orchestra in virtual reality

Zöllner, Michael; Krause, Moritz; Gemeinhardt, Jan; Bosl, Markus; Widmann, Dirk (2023)

25th International Conference on Human-Computer Interaction - Workshop on Interactive Technologies for Music Analysis and Visualization.


Peer Reviewed
 

The project Symotiv’s (http://symotiv.de) goal is to describe the complex function of a symphony through an interactive experience of the orchestra’s digital twin. We are capturing the musicians, their instruments and their sounds with machine learning based 3D human pose estimation and visualize them in Virtual Reality in a three-dimensional, virtual concert hall. Our audience steps into the role of the conductor and experience the scene and the sound from a perspective within the orchestra. This opens the possibility of experiencing and understanding what is happening from new spatial, but above all sonic perspectives.

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Preliminary Studies and Prototypes for Machine Learning based Evaluation of Surfers’ Performance on River Waves

Zöllner, Michael; Krause, Moritz; Gemeinhardt, Jan; Döllinger, Michael...

25th International Conference on Human-Computer Interaction - Late Breaking Work.


Peer Reviewed
 

In this paper we are describing our preliminary studies and proto- types for evaluating a surfer’s performance on a stationary wave. We are briefly describing the sport’s environment and development and the current state-of- the-art of machine learning based single camera tracking approaches we have evaluated and applied. The main part of the paper deals with the first implemen- tation, the tracking and the results of the evaluation of the movements of two surfers. We are closing with our lessons learned and our next steps.

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Understanding a Symphony Orchestra by Reexperience in Virtual Reality

Zöllner, Michael; Gemeinhardt, Jan; Bosl, Markus; Widmann, Dirk (2023)

25th International Conference on Human-Computer Interaction - Late Breaking Work.


Peer Reviewed
 

The aim of the project Symotiv (http://symotiv.de) is to introduce people to classical music through interaction with a virtual orchestra. With the help of Virtual Reality, it does not only enable to immerse oneself in a three-dimensional, virtual concert hall, but also to experience images and sound from the perspective of a musician. This opened the possibility of experiencing and understanding what is happening from new spatial, but above all sonic perspectives. Therefore, we developed a workflow to capture the motions and sound of 50 musicians and the conductor by using a camera-based Machine Learning approach.

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Marketing Strategies on Macro-Environment Levels- Success Determinants and Post Marketing Plan Improvisation during Global Trade Policy Changes

Falkenreck, Christine; Wagner, Ralf (2023)

Conference Proceeding, Global Marketing Conference Seoul, South Korea 2023.


Peer Reviewed

Wasserstoff aus biogenen Reststoffen - Stand der Technik und aktuelle Praxisprojekte

Gradel, Andy; Plessing, Tobias (2023)


 

Symposium der BMWK-Energieforschungsnetzwerke, Berlin


Rare Diseases in Citizen Science – Preliminary Experiences in Developing a Personal Health App

Schaaf, Jannik; Zerr, Thomas; Khouri, Andreas; Scheidt, Jörg; Neff, Michaela...

Studies in Health Technology and Informatics 310, S. 1151 - 1155.
DOI: 10.3233/SHTI231145


Open Access
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Nachbilddauer und elektrokortikale Parameter bei Migränepatienten - Einflüsse auf zukünftige Therapiemöglichkeiten?

Giesen, S.; Rimmele, F.; Jürgens, Tim Patrick; Müller, B.; Keller, A.; Scheidt, Jörg...

Nervenheilkunde 2023 41 (7).
DOI: 10.1055/s-0043-1770108


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Application of BIM in design review processes for buildings

Achenbach, Marcus; Rivas, Paul; Weber, Beatrix (2023)

Biondini & Frangopol (Eds): Life-Cycle of Structures and Infrastructure Systems, IALCEE, Eighth International Symposium on Life-Cycle Civil Engineering, July 2-6, 2023.
DOI: 10.1201/9781003323020-413


Open Access Peer Reviewed
 

The design review process - as part of the building permit - is mandatory for numerous construction projects in Germany. The paper-based review process is currently state of the art due to the obligation of documentation by law with legally binding signatures, e.g. for the construction process.

The application of BIM in the construction industry is increasing. Though the process of model sharing is specified in EN ISO 19650-4, the integration of the design review process has not been examined using BIM yet. In the review process, it is necessary to check structural analysis and other documents, too. Hence, the process of design review using various documents shall be linked to the steps proposed in ISO 19650-4.

The authors recommend a BIM-based digitalized design review process based on ISO 19650-4. lt is shown how the template for the review process can be adjusted to legal requirements for digital proceedings and can be used for the complete life cycle of a building better than the paper-based documentation.

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Zertifikatslehrgang „Der Weg zur Schwammstadt – Stadtentwicklung in Zeiten des Klimawandels“

Müller-Czygan, Günter; Schmidt, Michael (2023)

ANLiegen Natur 2023 (45(2)), S. 17-20.


Open Access

Wasserstoff aus Biomasse - Stand der Technik und Reifegrade unterschiedlicher Technologien

Gradel, Andy; Plessing, Tobias (2023)


 

31. C.A.R.M.E.N. Symposium, Würzburg


Legal governance for BIM - rights management and lawful data use

Weber, Beatrix; Achenbach, Marcus (2023)

Biondini & Frangopol (Eds): Life-Cycle of Structures and Infrastructure Systems, IALCEE, Eighth International Symposium on Life-Cycle Civil Engineering 2023.
DOI: 10.1201/9781003323020-402


Open Access Peer Reviewed
 

Tue use of BIM-modeling (BIM) within the building life cycle depends on different (specialist) models as well as a detailed as-built-model. The legally compliant transfer of data and models is decisive for the vision of a consistent use of BIM. Past legal research has mainly dealt with the question of copy and IP rights in contracts. The new EU legal framework of data law is now a game changer as codified legal rules for data use are on their way. The paper will reflect these requirements and link them to the relevant ISO norms. The paper will show how legal governance of BIM-models can be designed by a consistent model rights management which is linked to the technical delivery of information and present guidelines for a legally compliant transfer of BIM-models and data, promoting the trustworthy sharing of data and models within the building life cycle.

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Evaluation of Machine Learning based Pose Estimation of Surfers on River Waves

Zöllner, Michael; Kniesburges, Stefan; Krause, Moritz; Döllinger, Michael...

PETRA '23: Proceedings of the 16th International Conference on PErvasive Technologies Related to Assistive Environments 2023.
DOI: 10.1145/3594806


Peer Reviewed
 

In this work we are describing our preliminary experimental evaluation of open-source machine learning based pose estimation solutions for tracking a surfer’s skeleton on a stationary wave. We are briefly describing the sport’s environment and development and the current state-of-the-art of machine learning based single camera 2D and 3D pose estimation solutions. The main part of the paper deals with the experiment’s setup and the interpretation of the resulting data of the movements of one surfer. We are closing with our lessons learned and our next steps. 

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Befragung unter Videodienstanbietern zur Erprobung der Telepflege nach § 125a SGB XI

Wolff, Dietmar (2023)

„Befragung unter Videodienstanbietern zur Erprobung der Telepflege nach § 125a SGB XI“, FINSOZ e.V., Berlin Juli 2023 2023.


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Die Wärmepumpe - Funktionsweise und Einsatzgrenzen

Dölz, Michael (2023)


 

Nacht der Wissenschaften, Hof, 23.06.2023


Forschung und Entwicklung

Hochschule für Angewandte Wissenschaften Hof

Alfons-Goppel-Platz 1
95028 Hof

T +49 9281 409 - 4690
valentin.plenk[at]hof-university.de

Support of publications

Daniela Stock

T 09281 409 – 3042
daniela.stock.2[at]hof-university.de